Observe the following complexes
From the above, the number of inner orbital complexes with paramagnetic nature is
Text Solution
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is a strong-field ligand so it pairs the electrons. Thus,
Thus, it is an inner-orbital but a diamagnetic complex.
will pair - up the electrons so :-
Thus, it is an inner-orbital and a paramagnetic complex.
is a weak-field ligand so :-
Thus, it is an outer-orbital and paramagnetic complex
is a weak-field ligand so :-
Thus, it is an inner-orbital and paramagnetic complex
and 
is a strong-field ligand.
Thus,
Thus, it is an inner-orbital and diamagnetic complex.
and 
is a weak-field ligand.
Thus,
Thus, it is an outer-orbital and paramagnetic complex. Therefore, there are two inner-orbital and paramagnetic complexes.
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